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雙環(huán)辛烯氯化銠二聚體 CAS號：12279-09-3
發(fā)布時間: 2020-04-21 22:58
簡介
Chlorobis(cyclooctene)rhodium dimer is an organorhodium compound with the formula Rh2Cl2(C8H14)4, where C8H14 is cis-cyclooctene. Sometimes abbreviated Rh2Cl2(coe)4, it is a red-brown, air-sensitive solid that is a precursor to many other organorhodium compounds and catalysts.
The complex is prepared by treating an alcohol solution of hydrated rhodium trichloride with cyclooctene at room temperature. The coe ligands are easily displaced by other more basic ligands, more so than the diene ligands in the related complex cyclooctadiene rhodium chloride dimer.
The complex is prepared by treating an alcohol solution of hydrated rhodium trichloride with cyclooctene at room temperature. The coe ligands are easily displaced by other more basic ligands, more so than the diene ligands in the related complex cyclooctadiene rhodium chloride dimer.
基本信息
| 中文名稱 | 雙環(huán)辛烯氯化銠二聚體 | 英文名稱 | Chlorobis(cyclooctene)rhodium(I) dimer |
|---|---|---|---|
| 中文別名 |
雙環(huán)辛烯氯化銠(I)二聚體;氯化雙(環(huán)辛烯)釕;雙(環(huán)辛烯)氯化銠(I)二聚體; |
英文別名 |
Chlorobis(cyclooctene)rhodium(I) Dimer;Chlorobis(cyclooctene)rhodium(I),dimer;[Rh(coe)2Cl]2;cyclooctene,rhodium,dichloride; |
| CAS號 | 12279-09-3 | 分子式 | C32H56Cl2Rh2 |
| 分子量 | 717.50400 | 精確質(zhì)量 | 716.18700 |
| PSA | 0.00000 | LOGP | 12.96620 |
物化性質(zhì)
熔點：190oC (dec.)
儲存條件：Freezer
儲存條件：Freezer
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